SELECT 
  product_id, 
  parent_product_id 
FROM 
  cscart_product_variation_group_products 
WHERE 
  parent_product_id = 431514

Query time 0.00066

JSON explain

{
  "query_block": {
    "select_id": 1,
    "cost_info": {
      "query_cost": "5.62"
    },
    "table": {
      "table_name": "cscart_product_variation_group_products",
      "access_type": "ref",
      "possible_keys": [
        "idx_parent_product_id"
      ],
      "key": "idx_parent_product_id",
      "used_key_parts": [
        "parent_product_id"
      ],
      "key_length": "3",
      "ref": [
        "const"
      ],
      "rows_examined_per_scan": 23,
      "rows_produced_per_join": 23,
      "filtered": "100.00",
      "using_index": true,
      "cost_info": {
        "read_cost": "1.02",
        "eval_cost": "4.60",
        "prefix_cost": "5.62",
        "data_read_per_join": "368"
      },
      "used_columns": [
        "product_id",
        "parent_product_id"
      ]
    }
  }
}

Result

product_id parent_product_id
431515 431514
431516 431514
431517 431514
431518 431514
431519 431514
431520 431514
431521 431514
431522 431514
431523 431514
431524 431514
431525 431514
431526 431514
431527 431514
431528 431514
431529 431514
431530 431514
431531 431514
431532 431514
431533 431514
431534 431514
431535 431514
431536 431514
431537 431514